Facile synthesis and characterization of multi-walled carbon nanotubes decorated with hydroxyapatite from cattle horns for adsorptive removal of fluoride.
| dc.contributor.author | Ojok, Walter | |
| dc.contributor.author | Bolender, James P. | |
| dc.contributor.author | Wasswa, John | |
| dc.contributor.author | Ntambi, Emmanuel | |
| dc.contributor.author | Wanasolo, William | |
| dc.contributor.author | Moodley, Brenda | |
| dc.date.accessioned | 2023-07-31T10:53:00Z | |
| dc.date.available | 2023-07-31T10:53:00Z | |
| dc.date.issued | 2023-03-09 | |
| dc.description.abstract | Developing a new adsorbent for fluoride removal from cattle horn waste materials by a facile chemical method has shown great potential for fluoride removal. This paper reports the synthesis of multi-walled carbon nanotubes decorated with hydroxyapatite from cattle horns (MWCNT-CH) using a facile chemical method. Characterization studies using standard techniques showed that the composite is mesoporous with a rough morphology and contained MWCNTs uniformly encapsulated by the hydroxyapatite forming a crystalline MWCNT-CH composite. Optimization of fluoride adsorption by the as-synthesized composite using Response Surface Methodology (RSM) showed that a maximum fluoride removal efficiency of 80.21% can be attained at initial fluoride concentration = 10 mg/L, pH = 5.25, adsorbent dose = 0.5 g and a contact time of 78 min. ANOVA indicates contribution of the process variables in descending order as pH > contact time > adsorbent dose > initial fluoride concentration. Langmuir isotherm (R2 = 0.9991) best described the process, and the maximum adsorption capacity of fluoride onto the as-synthesized MWCNT-CH composite was 41.7 mg/g. Adsorption kinetics data were best fitted in the pseudo-second-order kinetic model (R2 = 0.9969), indicating chemisorption. The thermodynamic parameter ( H = 13.95 J/mol and S = 65.76 J/mol/K) showed that fluoride adsorption onto the MWCNT-CH composite was a spontaneous, endothermic, and entropy-driving process. Moreover, the adsorption mechanism involves ion exchange, electrostatic interaction, and hydrogen bonding. Fluoride was successfully desorbed (using 0.1 M NaOH) from the composite in four cycles, retaining fluoride removal efficiency in the fourth cycle of 57.3%. | en_US |
| dc.description.sponsorship | German Academic Exchange Service (DAAD) (Grant No. 91672385) | en_US |
| dc.identifier.citation | Ojok, W., Bolender, J. P., Wasswa, J., Ntambi, E., Wanasolo, W., & Moodley, B. (2023). Facile synthesis and characterization of multi-walled carbon nanotubes decorated with hydroxyapatite from cattle horns for adsorptive removal of fluoride. Heliyon, 9(3). | en_US |
| dc.identifier.issn | 2405-8440 | |
| dc.identifier.uri | https://dir.muni.ac.ug/handle/20.500.12260/549 | |
| dc.language.iso | en | en_US |
| dc.publisher | Elsevier Ltd. | en_US |
| dc.subject | Cattle horn | en_US |
| dc.subject | Fluoride adsorption | en_US |
| dc.subject | Hydroxyapatite | en_US |
| dc.subject | Kinetics | en_US |
| dc.subject | Multi-walled carbon nanotubes | en_US |
| dc.subject | Response surface methodology | en_US |
| dc.title | Facile synthesis and characterization of multi-walled carbon nanotubes decorated with hydroxyapatite from cattle horns for adsorptive removal of fluoride. | en_US |
| dc.type | Article | en_US |